(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthaleneChloro(P-cymene)ruthenium chloride
(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthaleneChloro(P-cymene)ruthenium chloride
CAS: 145926-28-9
Molecular Formula: C54H46Cl2P2Ru
(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthaleneChloro(P-cymene)ruthenium chloride - Names and Identifiers
| Name | (R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthaleneChloro(P-cymene)ruthenium chloride |
| Synonyms | dichlororuthenium 1-isopropyl-4-methyl-benzene (R)-RuCl[(p-cymene)(BINAP)]Cl S-(-)-BINAP-Chloro(P-cymene)ruthenium chloride [1-(2-diphenylphosphanyl-1-naphthyl)-2-naphthyl]-diphenyl-phosphane (R)-(+)-2,2'-[Bis(diphenylphosphino)-1,1'-Binaphthyl]Chloro(P-cymene)ruthenium (R)-(+)-2,2'-[BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]CHLORO(P-CYMENE)RUTHENIUM (R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RU CHLORIDE [(R)-2,2'-BIS-(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]-CHLORO-(P-CYMENE)-RUTHENIUMCHLORIDE [(S)-2,2'-Bis-(diphenylphosphino)-1,1'-Binaphthyl]-Chloro-(P-cymene)-rutheniumchloride [(R)-2,2'-Bis-(diphenylphosphino)-1,1'-Binaphthyl]-Chloro-(P-cymene)-rutheniumchloride [(S)-2,2'-BIS-(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]-CHLORO-(P-CYMENE)-RUTHENIUMCHLORIDE (S)-(-)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE (R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE (R)-(+)-2,2'-Bis(Diphenylphosphino)-1,1'-Binaphthalenechloro(P-Cymene)Ruthenium Chloride (S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthaleneChloro(P-cymene)ruthenium chloride (R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthaleneChloro(P-cymene)ruthenium chloride Chloro[(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride Chloro[(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-Binaphthyl](P-cymene)ruthenium (II) chloride Chloro[(S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-Binaphthyl](P-cymene)ruthenium (II) chloride Chloro[(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride, [RuCl(p-cymene)((R)-binap)]Cl |
| CAS | 145926-28-9 |
| EINECS | 664-469-9 |
| InChI | InChI=1/C44H32P2.C10H14.2ClH.Ru/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;1-8(2)10-6-4-9(3)5-7-10;;;/h1-32H;4-8H,1-3H3;2*1H;/q;;;;+2/p-2 |
(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthaleneChloro(P-cymene)ruthenium chloride - Physico-chemical Properties
| Molecular Formula | C54H46Cl2P2Ru |
| Molar Mass | 928.87 |
| Melting Point | >100°C |
| Boling Point | 724.3°C at 760 mmHg |
| Flash Point | 419°C |
| Vapor Presure | 5.55E-20mmHg at 25°C |
| Appearance | Powder |
| Color | orange |
| Storage Condition | 2-8°C |
| Sensitive | Air Sensitive |
| Physical and Chemical Properties | Storage Conditions: Freezer (-20 °c) |
(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthaleneChloro(P-cymene)ruthenium chloride - Risk and Safety
| Hazard Symbols | Xn - Harmful |
| Risk Codes | R68/20/21/22 - R36/37/38 - Irritating to eyes, respiratory system and skin. R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed. |
| Safety Description | S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. |
| WGK Germany | 3 |
| HS Code | 28439000 |
(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthaleneChloro(P-cymene)ruthenium chloride - Introduction
(R)-( )-2,2 '-Bis(diphenylphosphino)-1,1'-binaphthaleneChloro(P-cymene)ruthenium chloride is an organometallic compound with the chemical formula C44H32Cl2P2Ru. It is a dark red crystal, soluble in some organic solvents.
(R)-( )-2,2 '-Bis(diphenylphosphino)-1,1'-binaphthaleneChloro(P-cymene)ruthenium chloride is usually used as a catalyst, it has a wide range of applications in organic synthesis reactions. It can catalyze olefin hydrogenation reaction, carbonylation reaction and olefin cyclization reaction. In addition, it can also be used for asymmetric catalytic reactions and asymmetric synthesis.
Preparation of (R)-( )-2,2 '-Bis(diphenylphosphino)-1,1'-binaphthaleneChloro(P-cymene) A common method of ruthenium chloride is to react [RuCl2(p-cymene)]2 with (DPPF), where p-cymene is a cycloheptanenated cyclic hydrocarbon and DPPF is Bis (diphenylphosphine) biphenyl.
For safety information,(R)-( )-2,2 '-Bis(diphenylphosphino)-1,1'-binaphthaleneChloro(P-cymene)ruthenium chloride is relatively stable under general conditions of use. However, in handling and use, it is still necessary to comply with laboratory safety practices and specifications, and avoid direct contact with eyes, skin and respiratory tract. At the same time, it should be operated in a well-ventilated place to avoid inhaling its vapor. If exposed to skin or inhaled, rinse immediately with water and seek medical advice.
(R)-( )-2,2 '-Bis(diphenylphosphino)-1,1'-binaphthaleneChloro(P-cymene)ruthenium chloride is usually used as a catalyst, it has a wide range of applications in organic synthesis reactions. It can catalyze olefin hydrogenation reaction, carbonylation reaction and olefin cyclization reaction. In addition, it can also be used for asymmetric catalytic reactions and asymmetric synthesis.
Preparation of (R)-( )-2,2 '-Bis(diphenylphosphino)-1,1'-binaphthaleneChloro(P-cymene) A common method of ruthenium chloride is to react [RuCl2(p-cymene)]2 with (DPPF), where p-cymene is a cycloheptanenated cyclic hydrocarbon and DPPF is Bis (diphenylphosphine) biphenyl.
For safety information,(R)-( )-2,2 '-Bis(diphenylphosphino)-1,1'-binaphthaleneChloro(P-cymene)ruthenium chloride is relatively stable under general conditions of use. However, in handling and use, it is still necessary to comply with laboratory safety practices and specifications, and avoid direct contact with eyes, skin and respiratory tract. At the same time, it should be operated in a well-ventilated place to avoid inhaling its vapor. If exposed to skin or inhaled, rinse immediately with water and seek medical advice.
Last Update：2024-04-10 22:29:15
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